La química en nuestros platos: el café

Autores/as

DOI:

https://doi.org/10.18800/quimica.202501.003

Palabras clave:

Café, Coffea arabica, Coffea canephora, Terpenos, Cafeína, Procesos de beneficio

Resumen

El consumo global de café ha experimentado un notable incremento en la última década. El elevado consumo de café a nivel mundial se atribuye principalmente a sus efectos psicoestimulantes, influenciados por factores genéticos, y la percepción de sus beneficios para la salud, aunque también se reconocen efectos adversos en algunos individuos. La compleja química del café, influenciada por el grano, el tostado y la preparación, impacta tanto su sabor como sus propiedades. Este artículo explora la química del café, desde las especies Arábica y Robusta y su origen, hasta los procesos de beneficio (húmedo/seco) que modifican el grano verde. Se analizan las transformaciones durante el tostado (reacción de Maillard) y cómo el tueste y la extracción afectan a compuestos como los diterpenos y la cafeína, y a las características sensoriales del café. Finalmente, se destaca el uso de algunas técnicas químicas para determinar el origen y la pureza del café, subrayando la relevancia de la química para comprender integralmente esta bebida.    

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Biografía del autor/a

  • Alfredo Milton Angeles-Boza, University of Connecticut, Estados Unidos de América

    Department of Chemistry and Institute of Materials Science, University of Connecticut, Storrs, CT, 06269, USA

Referencias

(1) International Coffee Organization. https://ico.org/ (accesso 2025-04-19).

(2) MIDAGRI. Café peruano conquista 52 mercados en el mundo y es el sustento de 223 mil familias. https://www.gob.pe/institucion/midagri/noticias/822680-cafe-peruano-conquista-52-mercados-en-el-mundo-y-es-el-sustento-de-223-mil-familias (acceso 2025-04-19).

(3) Dam, R. M. van; Hu, F. B.; Willett, W. C. Coffee, Caffeine, and Health. N. Engl. J. Med. 2020, 383 (4), 369–378. https://doi.org/10.1056/NEJMra1816604

(4) Qi, H.; Li, S. Dose–Response Meta-Analysis on Coffee, Tea and Caffeine Consumption with Risk of Parkinson’s Disease. Geriatr. Gerontol. Int. 2014, 14 (2), 430–439. https://doi.org/10.1111/ggi.12123

(5) Panza, F.; Solfrizzi, V.; Barulli, M. R.; Bonfiglio, C.; Guerra, V.; Osella, A.; Seripa, D.; Sabbà, C.; Pilotto, A.; Logroscino, G. Coffee, Tea, and Caffeine Consumption and Prevention of Late-Life Cognitive Decline and Dementia: A Systematic Review. J. Nutr. Health Aging 2015, 19 (3), 313–328. https://doi.org/10.1007/s12603-014-0563-8

(6) Yuan, S.; Larsson, S. C. Coffee and Caffeine Consumption and Risk of Kidney Stones: A Mendelian Randomization Study. Am. J. Kidney Dis. 2022, 79 (1), 9-14.e1. https://doi.org/10.1053/j.ajkd.2021.04.018

(7) Cornelis, M. C.; van Dam, R. M. Genetic Determinants of Liking and Intake of Coffee and Other Bitter Foods and Beverages. Sci. Rep. 2021, 11 (1), 23845. https://doi.org/10.1038/s41598-021-03153-7

(8) Je, Y.; Liu, W.; Giovannuci, E. Coffee Consumption and Risk of Colorectal Cancer: A Systematic Review and Meta‐analysis of Prospective Cohort Studies. Int. J. Cancer 2009, 124 (7), 1662–1668. https://doi.org/10.1002/ijc.24124

(9) Davis, A. P.; Govaerts, R.; Bridson, D. M.; Stoffelen, P. An Annotated Taxonomic Conspectus of the Genus Coffea (Rubiaceae). Bot. J. Linn. Soc. 2006, 152 (4), 465–512. https://doi.org/10.1111/j.1095-8339.2006.00584.x

(10) Davis, A. P.; Rakotonasolo, F. Six New Species of Coffee (Coffea) from Northern Madagascar. Kew Bull. 2021, 76 (3), 497–511. https://doi.org/10.1007/s12225-021-09952-5

(11) Davis, A. P.; Kiwuka, C.; Faruk, A.; Walubiri, M. J.; Kalema, J. The Re-Emergence of Liberica Coffee as a Major Crop Plant. Nat. Plants 2022, 8 (12), 1322–1328. https://doi.org/10.1038/s41477-022-01309-5

(12) Antonio Fausto Naironi. De Saluberrima Potione Cahue, Seu Cafe; Typis Michaelis Herculis: Roma, 1671.

(13) Salojärvi, J.; Rambani, A.; Yu, Z.; Guyot, R.; Strickler, S.; Lepelley, M.; Wang, C.; Rajaraman, S.; Rastas, P.; Zheng, C.; Muñoz, D. S.; Meidanis, J.; Paschoal, A. R.; Bawin, Y.; Krabbenhoft, T. J.; Wang, Z. Q.; Fleck, S. J.; Aussel, R.; Bellanger, L.; Charpagne, A.; Fournier, C.; Kassam, M.; Lefebvre, G.; Métairon, S.; Moine, D.; Rigoreau, M.; Stolte, J.; Hamon, P.; Couturon, E.; Tranchant-Dubreuil, C.; Mukherjee, M.; Lan, T.; Engelhardt, J.; Stadler, P.; Correia De Lemos, S. M.; Suzuki, S. I.; Sumirat, U.; Wai, C. M.; Dauchot, N.; Orozco-Arias, S.; Garavito, A.; Kiwuka, C.; Musoli, P.; Nalukenge, A.; Guichoux, E.; Reinout, H.; Smit, M.; Carretero-Paulet, L.; Filho, O. G.; Braghini, M. T.; Padilha, L.; Sera, G. H.; Ruttink, T.; Henry, R.; Marraccini, P.; Van de Peer, Y.; Andrade, A.; Domingues, D.; Giuliano, G.; Mueller, L.; Pereira, L. F.; Plaisance, S.; Poncet, V.; Rombauts, S.; Sankoff, D.; Albert, V. A.; Crouzillat, D.; de Kochko, A.; Descombes, P. The Genome and Population Genomics of Allopolyploid Coffea Arabica Reveal the Diversification History of Modern Coffee Cultivars. Nat. Genet. 2024, 56 (4), 721–731. https://doi.org/10.1038/s41588-024-01695-w

(14) Carvalho, A.; Krug, C. A.; Mendes, J. E. T.; Antunes Filho, H.; Morais, H. de; Aloisi Sobrinho, J.; Morais, M. V. de; Rocha, T. R. da. Melhoramento do cafeeiro: IV - Café Mundo Novo. Bragantia 1952, 12, 97–130. https://doi.org/10.1590/S0006-87051952000200001

(15) Martins, A. L. História do café; Editora Contexto: São Paulo, 2015.

(16) Pendergrast, M. Uncommon Grounds: The History of Coffee and How It Transformed Our World; Basic Books: New York, 2010.

(17) Lécolier, A.; Besse, P.; Charrier, A.; Tchakaloff, T.-N.; Noirot, M. Unraveling the Origin of Coffea Arabica ‘Bourbon Pointu’ from La Réunion: A Historical and Scientific Perspective. Euphytica 2009, 168 (1), 1–10. https://doi.org/10.1007/s10681-009-9886-7

(18) Clarindo, W. R.; Carvalho, C. R.; Caixeta, E. T.; Koehler, A. D. Following the Track of “Híbrido de Timor” Origin by Cytogenetic and Flow Cytometry Approaches. Genet. Resour. Crop Evol. 2013, 60 (8), 2253–2259. https://doi.org/10.1007/s10722-013-9990-3

(19) Angélico, C. L.; Pimenta, C. J.; Chalfoun, S. M.; Chagas, S. J. de R.; Pereira, M. C.; Chalfoun, Y. Different stages of maturity and times of bagging in relation to quality of coffee. Coffee Science. 2011. 6(1). 8-19. https://coffeescience.ufla.br/index.php/Coffeescience/article/view/37

(20) Illy, A.; Viani, R. Espresso Coffee, The Science of Quality, Second ed. Academic Press: California, 2005.

(21) Bytof, G.; Knopp, S.-E.; Kramer, D.; Breitenstein, B.; Bergervoet, J. H. W.; Groot, S. P. C.; Selmar, D. Transient Occurrence of Seed Germination Processes during Coffee Post-Harvest Treatment. Ann. Bot. 2007, 100 (1), 61–66. https://doi.org/10.1093/aob/mcm068

(22) Bytof, G.; Knopp, S.-E.; Schieberle, P.; Teutsch, I.; Selmar, D. Influence of Processing on the Generation of γ-Aminobutyric Acid in Green Coffee Beans. Eur. Food Res. Technol. 2005, 220 (3), 245–250. https://doi.org/10.1007/s00217-004-1033-z

(23) Haile, M.; Kang, W. H. The Role of Microbes in Coffee Fermentation and Their Impact on Coffee Quality. J. Food Qual. 2019, 2019 (1), 4836709. https://doi.org/10.1155/2019/4836709

(24) Minten, B.; Assefa, T.; Hirvonen, K. Can Agricultural Traders Be Trusted? Evidence from Coffee in Ethiopia. World Dev. 2017, 90, 77–88. https://doi.org/10.1016/j.worlddev.2016.08.018

(25) Anderson, K. A.; Smith, B. W. Chemical Profiling To Differentiate Geographic Growing Origins of Coffee. J. Agric. Food Chem. 2002, 50 (7), 2068–2075. https://doi.org/10.1021/jf011056v

(26) Campa, C.; Ballester, J. F.; Doulbeau, S.; Dussert, S.; Hamon, S.; Noirot, M. Trigonelline and Sucrose Diversity in Wild Coffea Species. Food Chem. 2004, 88 (1), 39–43. https://doi.org/10.1016/j.foodchem.2004.01.020

(27) Procida, G.; Lagazio, C.; Cateni, F.; Zacchigna, M.; Cichelli, A. Characterization of Arabica and Robusta Volatile Coffees Composition by Reverse Carrier Gas Headspace Gas Chromatography–Mass Spectrometry Based on a Statistical Approach. Food Sci. Biotechnol. 2020, 29 (10), 1319–1330. https://doi.org/10.1007/s10068-020-00779-7

(28) Ángeles-Boza, A. M. La química en nuestros platos: los preservantes. Rev. Quím. 2022, 36 (1), 35–41. https://revistas.pucp.edu.pe/index.php/quimica/article/view/25324

(29) Lund, M. N.; Ray, C. A. Control of Maillard Reactions in Foods: Strategies and Chemical Mechanisms. J. Agric. Food Chem. 2017, 65 (23), 4537–4552. https://doi.org/10.1021/acs.jafc.7b00882

(30) Cardoso, W. S.; Dias, S. R.; Coelho, V. S.; Pereira, L. L.; Fioresi, D. B.; Pinheiro, F. de A. Maillard Reaction Precursors and Arabica Coffee (Coffea Arabica L.) Beverage Quality. Food Humanity 2023, 1, 1–7. https://doi.org/10.1016/j.foohum.2023.01.002

(31) Król, K.; Gantner, M.; Tatarak, A.; Hallmann, E. The Content of Polyphenols in Coffee Beans as Roasting, Origin and Storage Effect. Eur. Food Res. Technol. 2020, 246 (1), 33–39. https://doi.org/10.1007/s00217-019-03388-9

(32) Lindsey, Z. R.; Williams, J. R.; Burgess, J. S.; Moore, N. T.; Splichal, P. M. Caffeine Content in Filter Coffee Brews as a Function of Degree of Roast and Extraction Yield. Sci. Rep. 2024, 14 (1), 29126. https://doi.org/10.1038/s41598-024-80385-3

(33) Bolka, M.; Emire, S. Effects of Coffee Roasting Technologies on Cup Quality and Bioactive Compounds of Specialty Coffee Beans. Food Sci. Nutr. 2020, 8 (11), 6120–6130. https://doi.org/10.1002/fsn3.1904

(34) Seninde, D. R.; Chambers, E. Coffee Flavor: A Review. Beverages 2020, 6 (3), 44. https://doi.org/10.3390/beverages6030044

(35) Novaes, F. J. M.; da Silva, M. A. E.; Silva, D. C.; Aquino Neto, F. R. de; Rezende, C. M. Extraction of Diterpene-Phytochemicals in Raw and Roasted Coffee Beans and Beverage Preparations and Their Relationship. Plants Basel Switz. 2023, 12 (8), 1580. https://doi.org/10.3390/plants12081580

(36) Urgert, R.; van der Weg, G.; Kosmeijer-Schuil, T. G.; van de Bovenkamp, P.; Hovenier, R.; Katan, M. B. Levels of the Cholesterol-Elevating Diterpenes Cafestol and Kahweol in Various Coffee Brews. J. Agric. Food Chem. 1995, 43 (8), 2167–2172. https://doi.org/10.1021/jf00056a039

(37) Heckers, H.; Göbel, U.; Kleppel, U. End of the Coffee Mystery: Diterpene Alcohols Raise Serum Low-Density Lipoprotein Cholesterol and Triglyceride Levels. J. Intern. Med. 1994, 235 (2), 192–193. https://doi.org/10.1111/j.1365-2796.1994.tb01058.x

(38) Hamer, M. Coffee and Health: Explaining Conflicting Results in Hypertension. J. Hum. Hypertens. 2006, 20 (12), 909–912. https://doi.org/10.1038/sj.jhh.1002076

(39) McCusker, R. R.; Fuehrlein, B.; Goldberger, B. A.; Gold, M. S.; Cone, E. J. Caffeine Content of Decaffeinated Coffee. J. Anal. Toxicol. 2006, 30 (8), 611–613. https://doi.org/10.1093/jat/30.8.611

(40) Olechno, E.; Puścion-Jakubik, A.; Zujko, M. E.; Socha, K. Influence of Various Factors on Caffeine Content in Coffee Brews. Foods 2021, 10 (6), 1208. https://doi.org/10.3390/foods10061208

(41) Nehlig, A. Interindividual Differences in Caffeine Metabolism and Factors Driving Caffeine Consumption. Pharmacol. Rev. 2018, 70 (2), 384–411. https://doi.org/10.1124/pr.117.014407

(42) Pons, G.; Blais, J. C.; Rey, E.; Plissonnier, M.; Richard, M. O.; Carrier, O.; d’Athis, P.; Moran, C.; Badoual, J.; Olive, G. Maturation of Caffeine N-Demethylation in Infancy: A Study Using the 13CO2 Breath Test. Pediatr. Res. 1988, 23 (6), 632–636. https://doi.org/10.1203/00006450-198806000-00021

(43) Bory, C.; Baltassat, P.; Porthault, M.; Bethenod, M.; Frederich, A.; Aranda, J. V. Metabolism of Theophylline to Caffeine in Premature Newborn Infants. J. Pediatr. 1979, 94 (6), 988–993. https://doi.org/10.1016/S0022-3476(79)80246-2

(44) Anderson, K. A.; Smith, B. W. Chemical Profiling To Differentiate Geographic Growing Origins of Coffee. J. Agric. Food Chem. 2002, 50 (7), 2068–2075. https://doi.org/10.1021/jf011056v

(45) Wei, F.; Furihata, K.; Koda, M.; Hu, F.; Kato, R.; Miyakawa, T.; Tanokura, M. 13C NMR-Based Metabolomics for the Classification of Green Coffee Beans According to Variety and Origin. J. Agric. Food Chem. 2012, 60 (40), 10118–10125. https://doi.org/10.1021/jf3033057

(46) Carter, J. F.; Yates, H. S. A.; Tinggi, U. Isotopic and Elemental Composition of Roasted Coffee as a Guide to Authenticity and Origin. J. Agric. Food Chem. 2015, 63 (24), 5771–5779. https://doi.org/10.1021/acs.jafc.5b01526

(47) Techer, I.; Lancelot, J.; Descroix, F.; Guyot, B. About Sr Isotopes in Coffee ‘Bourbon Pointu’ of the Réunion Island. Food Chem. 2011, 126 (2), 718–724. https://doi.org/10.1016/j.foodchem.2010.11.035

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Publicado

2025-06-30

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Cómo citar

La química en nuestros platos: el café. (2025). Revista de Química, 39(1), 37-47. https://doi.org/10.18800/quimica.202501.003