Pyrolysis of Plastic And Mixed Waste as a Sustainable Alternative for Municipal Solid Waste Management

Authors

DOI:

https://doi.org/10.18800/kawsaypacha.202601.A013

Keywords:

Pyrolysis, Thermochemistry, Urban solid waste, Circular economy, El Salvador

Abstract

This literature review analyzes pyrolysis as a sustainable and technological tool for the management of municipal solid waste, especially plastics, biomass, and mixed waste. A reading of 131 open-access scientific studies indexed in the Dimensions database was done, of which 29 were considered evidence of how pyrolysis transforms waste into useful products such as biochar, bio-oil, and combustible gases, contributing to energy generation. Mixed waste containing plastics with low or no biodegradability that increases its energy yield, and is further enhanced by some catalysts such as zeolites that increase the efficiency of the process. Biochar stands out not only as a fuel but also for its ability to improve soil properties. Bio-oils can be used as a raw material for other fuels such as biodiesel, and combustible gases can be used as a source of fire or in internal combustion engines. In addition, the important variables of each study are summarized for subsequent replication or discussion, such as pyrolysis temperature, waste composition, and residence time. In order to reduce the volume of waste in landfills and encourage the use of renewable energy, this research encourages strengthening cooperation among researchers, the development of public policies that promote environmental quality, and cooperation with authorities and communities to make this solution viable and an opportunity to generate ecological value by mitigating plastics, and energy value by synthesizing information about al alternative to fossil fuels.

Downloads

Download data is not yet available.

References

Adeniyi, A.; Iwuozor, K.; Emenike, E.; Ajala, O.; Ogunniyi, S. & Muritala, K. (2024). Thermochemical co-conversion of biomass-plastic waste to biochar: a review. Green Chemical Engineering, 5(1), pp. 31-49. https://doi.org/10.1016/j.gce.2023.03.002

Ansah, E.; Wang, L. & Shahbazi, A. (2016). Thermogravimetric and calorimetric characteristics during co-pyrolysis of municipal solid waste components. Waste Management, 56, pp. 196-206. https://doi.org/10.1016/j.wasman.2016.06.015

Bansode, R.; Randolph, P.; Hassan, O.; Rehrah, D. & Ahmedna, M. (2016). Mixed Solid Municipal Waste-Based Biochar for Soil Fertility and Greenhouse Gas Mitigation. https://www.researchgate.net/publication/334802374_Mixed_Solid_Municipal_Waste-Based_Biochar_for_Soil_Fertility_and_Greenhouse_Gas_Mitigation 1

Dafalla, M.; Inayat, A.; Jamil, F. & Ghenai, C. (2024). Prospective of biochar material production and process optimization using co-pyrolysis approach-A mini-review. Journal of Physics: Conference Series 2751, 01202. https://doi.org/10.1088/1742-6596/2751/1/012024

Diallo, A.; Alkhatib, M.; Alam, Z. & Mel, M. (2021). Enhancement of the calorific value of Em1707pty Fruit Bunch (Efb) by adding municipal solid waste as solid fuel in gasification process. IIUM Engineering Journal, 22(2), pp. 10-20. https://doi.org/10.31436/iiumej.v22i2.1566

Gabbar, H. & Ahmad, M. (2024). Integrated Waste-to-Energy Process Optimization for Municipal Solid Waste. Energies, 17(2), p. 497. https://doi.org/10.3390/en17020497

Hardiyanto, M.; Sasongko, N. & Almubaroq, H. (2023). Analysis Of Isothermal Pyrolysis Process Of Municipal Waste Into Bio-Oil With The Addition Of Natural Catalyst (Zeolite) In Supporting National Energy Security. IOP Conf. Series: Earth and Environmental Science 1267, 012077. https://doi.org/10.1088/1755-1315/1267/1/012077

Holubčík, M.; Klačko, A.; Jandačka, J. & Drga, J. (2022). Pyrolysis Treatment of Municipal Solid Waste and Automotive Waste with Study of Each Component Energy Potential. MATEC Web of Conferences, 369. https://doi.org/10.1051/matecconf/202236903005

Horváth, D.; Tomasek, S.; Bobek-Nagy, J.; Tóth, E.; Kurdi, R. & Miskolczi, N. (2024). Syngas Purpose Pyrolysis‐Gasification of Organic Fractions of MSW over Metal‐Loaded Y‐Zeolite Catalysts. International Journal of Energy Research, 5558323. https://doi.org/10.1155/2024/5558323

Iannello, S.; Morrin, S. & Materazzi, M. (2020). Fluidised Bed Reactors for the Thermochemical Conversion of Biomass and Waste. KONA Powder and Particle Journal. https://doi.org/10.14356/kona.2020016

Islam, K.; Khatun, M.; Arefin, A.; Islam, M. & Hassan, M. (2021). Waste to energy: An experimental study of utilizing the agricultural residue, MSW, and e-waste available in Bangladesh for pyrolysis conversión. Heliyon, 7(12), e08530. https://doi.org/10.1016/j.heliyon.2021.e08530

Klavins, M.; Bisters, V. & Burlakovs, J. (2018). Small Scale Gasification Application and Perspectives in Circular Economy. Environmental and Climate Technologies, 22(1). https://doi.org/10.2478/rtuect-2018-0003

Khatibi, M.; Nahil, M. & Williams, P. (2025). Pyrolysis/Non-thermal Plasma/Catalysis Processing of Refuse-Derived Fuel for Upgraded Oil and Gas Production. Waste and Biomass Valorization, 16, pp. 3267-3294. https://doi.org/10.1007/s12649-024-02866-w

Li, Y. & Williams, P. (2023). Catalytic Biochar and Refuse-Derived Char for the Steam Reforming of Waste Plastics Pyrolysis Volatiles for Hydrogen-Rich Syngas. Industrial & Engineering Chemistry Research, 62(36). https://doi.org/10.1021/acs.iecr.3c02292

Márquez, A.; Patlaka, E.; Sfakiotakis, S.; Ortiz, I. & Sánchez-Hervás, J. (2023). Pyrolysis of municipal solid waste: A kinetic study through multi-step reaction models. Waste management, 172, pp. 171-181. https://doi.org/10.1016/j.wasman.2023.10.031

Mensah, I.; Ahiekpor, J.; Bensah, E.; Narra, S.; Amponsem, B. & Antwi, E. (2022). Recent Development of Biomass and Plastic Co-Pyrolysis for Syngas Production. Chemical Science International Journal, 31(1), pp. 41-59. https://doi.org/10.9734/CSJI/2022/v31i130275. 10.9734/csji/2022/v31i130275

Miskolczi, N.; Gao, N. & Quan, C. (2023). Pyrolysis-gasification of biomass and Municipal Plastic Waste using transition metal modified catalyst to investigate the effect of contaminants. Journal of the Energy Institute, 108. https://doi.org/10.1016/j.joei.2023.101233

Miskolczi, N.; Gao, N.; Quan, C. & Laszlo, A. (2025). CO2 reduction by chars obtained by pyrolysis of real wastes: Low temperature adsorption and high temperature CO2 capture. Carbon Capture Science & Technology, 14. https://doi.org/10.1016/j.ccst.2024.100332

Nanda, S.; Sarker, T.; Kang, K.; Li, D. & Dalai, A. (2023). Perspectives on Thermochemical Recycling of End-of-Life Plastic Wastes to Alternative Fuels. Materials, 16(13), 4563. https://doi.org/10.3390/ma16134563

Netzer, C.; Li, T. & Løvås, T. (2021). Surrogate Reaction Mechanism for Waste Incineration and Pollutant Formation. Energy & Fuels, 35(9). https://doi.org/10.1021/acs.energyfuels.0c03485

Papuga, S.; Musić, I.; Gvero, P. & Vukić, L. (2013). Preliminary research of waste biomass and plastic pyrolysis process. https://doi.org/10.7251/comen1301076p

Park, S.; Lee, J.; Yang, W.; Kang, J.; Sung, J.; Alam, M.; Seo, Y.; Rao, C.; Saravanakumar, A.; Kumar, K.; Lee, J. & Oh, J. (2016). For Waste to Energy, Assessment of Fluff Type Solid Refuse Fuel by Thermal Characteristics Analyses. Procedia Environmental Sciences, 35, pp. 498-505. https://doi.org/10.1016/j.proenv.2016.07.034

Sebestyén, Z.; Miskolczi, N.; Barta-Rajnai, E.; Jakab, E. & Czégény, Z. (2017). Thermocatalytic Studies on Municipal Solid Waste. Energy Procedia, 105, pp. 706-711. https://doi.org/10.1016/j.egypro.2017.03.379

Sophonrat, N. & Yang, W. (2017). Effect of mixing methods of polyethylene and cellulose on volatile products from its co-pyrolysis. Energy Procedia, 142, pp. 315-320. https://doi.org/10.1016/j.egypro.2017.12.050

Syamsiro, M.; Saptoadi, H.; Norsujianto, T.; Noviasri, P.; Cheng, S.; Alimuddin, Z. & Yoshikawa, K. (2014). Fuel Oil Production from Municipal Plastic Wastes in Sequential Pyrolysis and Catalytic Reforming Reactors. Energy Procedia, 47, pp. 180-188. https://doi.org/10.1016/j.egypro.2014.01.212

Wee, M.; Chin, B.; Saptoro, A.; Chew, J.; Sunarso, J.; Yusup, S. & Sharma, A. (2024). Catalytic co-pyrolysis of oil palm empty fruit bunches (EFB) and surgical face mask (SFM) wastes: Thermo-kinetic study, ANN model fitting, and synergistic effect. Journal of the Taiwan Institute of Chemical Engineers, 165. https://doi.org/10.1016/j.jtice.2024.105811

Zhang, H.; Tian, B.; Yan, X.; Bai, Y.; Gao, J.; Li, X.; Xie, Q.; Yang, Y. & Li, Y. (2023). Copyrolysis of Waste Cartons and Polyolefin Plastics under Microwave Heating and Characterization of the Products. ACS Omega, 8(8). https://doi.org/10.1021/acsomega.2c05045

Zhao, X.; Li, K. E.; Lamm, M.; Celik, S.; Wei, L. & Ozcan, S. (2021). Solid Waste Gasification: Comparison of Single- and Multi-Staged Reactors. En Gasification [Working Title]. IntechOpen. https://doi.org/10.5772/intechopen.96157

Zhou, H.; Wu, C.; Onwudili, J.; Meng, A.; Zhang, Y. & Williams, P. (2014). Polycyclic aromatic hydrocarbons (PAH) formation from the pyrolysis of different municipal solid waste fractions. Waste Management, 36, pp. 136-146. https://doi.org/10.1016/j.wasman.2014.09.014

Published

2026-05-22

How to Cite

Alvarenga Aguilar, L. A. (2026). Pyrolysis of Plastic And Mixed Waste as a Sustainable Alternative for Municipal Solid Waste Management. Revista Kawsaypacha: Sociedad Y Medio Ambiente, (17), A-013. https://doi.org/10.18800/kawsaypacha.202601.A013

Issue

Section

ACADEMIC ARTICLES AND ESSAY